I’d probably go with Thanos, and I know he’s a pretty popular pick.

What makes him interesting is that, in his own mind, he isn’t trying to take over the universe or rule everyone. He genuinely believes he’s saving it. His idea is that by wiping out half of all life, there will be enough resources left for everyone else, preventing poverty, starvation, and entire civilizations from collapsing.
The part that really sets him apart from a lot of other villains is what happens after he succeeds. He doesn’t claim a throne or become some all-powerful ruler. Instead, he retires to a quiet life as a farmer, which shows that he never wanted fame, power, or wealth for himself. He honestly believed he had done what was necessary.
Even the way he carries out his plan reflects that mindset. The Snap is completely random, rich or poor, powerful or ordinary, no one gets special treatment. He doesn’t choose based on race, gender, or status. To Thanos, it’s the only fair way to do something so extreme, even if the idea itself is horrifying.
That’s what makes him such a compelling villain. His logic is deeply flawed, but from his perspective, he truly believes he’s the hero making the impossible choice for the greater good.

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